Cost-Competitive Hydrogen Generation with Pre-Combustion Carbon Capture

GTI Energy has piloted a hydrogen production process with an inherent capability for carbon dioxide (CO2) separation. The process is a cost-competitive, steam-neutral alternative to traditional steam methane reforming (SMR). It also produces a higher-quality hydrogen stream (>90%, which can be upgraded further) while eliminating the need for a water gas shift reactor. Furthermore, it also eliminates the costly amine system to separate the CO2. This eliminates the associated capital expenditure and operating expenses of amine-based systems required for CO2 capture from SMR and natural gas combined cycle (NGCC)-based power systems.

The concept for a 5MMSCFD (12,750 kg/day) modular demonstration plant has been defined and costs estimated for its construction and operation. The design is scalable to very large H2 production rates (e.g., 100MMSCFD [255,000 kg/day]) with the attendant economies of scale, with single or multiple modules.

Because the process has a byproduct of essentially pure CO2, it offers a cost-effective approach for pre-combustion carbon capture for a combined cycle power plant. GTI Energy performed a preliminary evaluation of a commercial power plant using H2 from GTI Energy’s process compared to a NGCC plant with carbon capture and a power plant using H2 from a traditional SRM with an amine based CO2 capture system.

Using GTI Energy’s H2 process with carbon capture will increase the cost of electricity by only 30%, making it the lowest cost carbon capture technology. The use of an advanced H2 turbine will further reduce costs.

GTI Energy has completed pilot testing (under DOE funding), which verified catalyst stability and successfully demonstrated SER chemistry and process operation. H2 purity and yield were at or above expected levels for the limited sorbent feed rates. The next step is to upgrade the pilot using an indirectly fired calciner, and demonstrate operations. In addition, GTI Energy is executing a hydrogen-to-power study for U.S. DOE with major OEM support.

Learn more about GTI Energy's hydrogen production process. (0.7MB pdf)

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